SCEA and SCEE have posted their initial
compatibility lists for the PlayStation (Vita) TV in their repective regions.
There are a few games
which work on the Vita TV over in Japan but which aren’t yet on either list:
Sword Art Online: Hollow Fragment (though I think it may have needed a separate patch update, which I hope may be included in this week's update in North America and Europe), the various games from the
Hyperdimension Neptunia series which are curently on Vita (
PP,
Re;Birth1,
Re;Birth2,
Geki Noire, and
U – the first two of which are available in the West),
Senran Kagura: Shinovi Versus (which is being released in North America on the same day as PSTV), and many others (such as
Danganronpa: Another Episode).
But then, these are initial lists only, so more games are likely to be added as time goes on.